Aerosol-assisted CVD of thioether-functionalised indium aminoalkoxides

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Aerosol-assisted CVD of thioether-functionalised indium aminoalkoxides

ABSTRACT Thioether-functionalised indium aminoalcoholates have been used as single-source precursors in aerosol-assisted CVD processes. The obtained In2O3-x S x oxysulphide deposits show either a single indium sulphide phase for deposits with high sulphide content [>75% (S/(S + O)) for the t-butyl derivatives] or pronounced phase separation in indium oxide and indium sulphide for lower sulphide...

متن کامل

Aerosol-assisted CVD of SnO from stannous alkoxide precursors.

The stannous alkoxides [Sn(OR)2] [R = i-Pr, t-Bu, C(Et)Me2, CHPh2, CPh3] have been synthesised by reaction of Sn(NR'2)2 with two equivalents of HOR [R' = Me, R = i-Pr; R' = SiMe3, R = t-Bu, C(Et)Me2, CHPh2, CPh3]. Single crystal X-ray diffraction analysis of the bis(diphenylmethoxide) (4) and bis(triphenylmethoxide) (5) species have shown them to comprise three-coordinate Sn(ii) centres through...

متن کامل

Trinuclear pyridyl functionalised hydroxylaminato complexes of aluminium, gallium and indium.

The reaction of the donor functionalised N,N-bis[2-(pyrid-2-yl)ethyl]hydroxylamine [HON(C2H4-o-py)2] and three equivalents of the Lewis-acids AlMe3, GaMe3 or InMe3 resulted in the formation of dimethylhydroxylaminato-metal complexes of the general constitution [MMe2ON(C2H4-o-py)2 x 2 MMe3] with M = Al (1), Ga (2) or In (3) by methane elimination. An alternative method to generate complexes 1 an...

متن کامل

Trends in Precursor Design for Conventional and Aerosol-assisted CVD of High-Tc Superconductors

Conventional MOCVD techniques require molecules displaying volatility and constant vapor pressure. Metal oxide precursors, i.e., b-diketonates, or classical or functionalized metal alkoxides are mostly solids. The various approaches used to tailor volatility are discussed with barium derivatives as an example. The relationships between sublimation temperature and molecular weight suggest that v...

متن کامل

Re(I) derivatives functionalised with thioether crowns containing the 1,10-phenanthroline subunit as a new class of chemosensors.

A series of luminescent fac-[Re(CO)3(L)(NN)](+) complexes, where L is a pyridine or an imidazole and NN is the 1,10-phenanthroline subunit of mixed donor pentadentate thioether crowns have been synthesised and their luminescence properties have been analysed. Then, heterometallic Re(i)/Au(i) complexes, with the Au(i) fragment bonded directly to the imidazole ligand, and heterometallic Re(i)/Ag(...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Monatshefte für Chemie - Chemical Monthly

سال: 2017

ISSN: 0026-9247,1434-4475

DOI: 10.1007/s00706-017-1980-2